Shop online for a wide selection of nbutyllithium, 2. Although chemists will still need to handle tbuli and its brethren with care, deep eutectic solvents can help them to guide tbulis cannonball reactivity with more arrowlike precision. Designed to stick to oily, greasy or irregular surfaces. Iarc no component of this product present at levels greater than or equal to 0. Hexane n hexane 20 72 as published by safe work australia. Hexanes typically contain a high proportion of nhexane. Relevant identified uses of the substance or mixture and uses advised against use of the substancemixture. The starting material is fairly soluble in the solvent, but not at all in hexane, which is how the nbuli usually comes, i was wondering if this could be an issue. Product and company identification product name n butyllithium, 2. Hexane is expected to rapidly volatilize leaving a deposit of nbutyllithium behind. Hexane not listed as a carcinogen by acgih, iarc, ntp, or ca prop 65. The term hexanes cas 110543 refers to a hydrocarbon distillation fraction that contains a mixture of linear and branched hexane isomers. Sensitivity to static discharge yes sensitivity to static impact not applicable.
Lithium hydroxide, the oxidationhydrolysis product, is considered moderately toxic. It is widely used as a polymerization initiator in the production of elastomers such as polybutadiene or styrenebutadienestyrene sbs. Hexane is expected to rapidly volatilize leaving a deposit of n butyllithium behind. Quenching of pyrophoric materials university of california. Twa the timeweighted average airborne concentration over an eighthour working day, for a fiveday working week over an entire working life. Hexane material safety data sheet cas no 110543 sdsmsds. Flammable limits in air not applicable for formulation. In iupac nomenclature, however, hexane is the unbranched isomer nhexane. Check availability and compare product details hexane chromasolv, for hplc. Reproductive effects experiments have shown reproductive toxicity effects on laboratory animals. The starting material is fairly soluble in the solvent, but not at all in hexane, which is how the n buli usually comes, i was wondering if this could be an issue.
None information in this msds is from available published sources and is believed to be accurate. Sigmaaldrich 9386 page 3 of 7 methods and materials for containment and cleaning up contain spillage, and then collect with noncombustible absorbent material, e. Preparation, properties, and safe handling of commercial. The interdependent properties, such as pyrophoricity, solubility, stability, and aggregation, are tabulated and discussed. Heating may cause a fire in contact with water releases flammable gases which may ignite spontaneously may cause fire or explosion. Nearly continuous exposure of animals at 250 ppm has caused. Extreme high moderate low section 1 chemical product and company identification.
Other companies are charging thousands of dollars to set up accounts and give you access to their msds online database. Your new online msds binder is a place for you to store the material safety data sheets you need to. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. The major use n hexane is to extract vegetable oils from crops due to its narrow distillation range and selective power. Butyllithium 15% solution in nhexane for synthesis find msds or sds, a coa, data sheets and more information. Hazard statements h225 highly flammable liquid and vapour. Common names for these solvents are commercial hexane, mixed hexanes, petroleum ether, and petroleum naphtha. Butyllithium 15% solution in n hexane for synthesis find msds or sds, a coa, data sheets and more information. Quenching of tbutyllithium tbuli remaining in bottle or left after reactions quenching of pyrophoric liquids, such as secbuli, nbuli, grignard reagents, remaining in bottle or left after reactions quenching of pyrophoric solids, such as finely divided metals magnesium, zirconium, nonmetals white phosphorus. Occupational polyneuropathy has resulted from hexane exposures as low as 500 ppm, but the minimum levels of n hexane that are neurotoxic in humans havent been established. Also, it is broadly employed as a strong base in the synthesis of organic compounds as in the pharmaceutical industry.
That was katrina kramer, speaking with eva hevia from the university of strathclyde about tertbutyl lithium or tbuli. Hexane 25 gkg rat 3000 mgkg rabbit 48000 ppm rat 4 h. Material safety data sheet hexane 7 section 16 other information msds creation date. Chemical intermediate for research and industrial use only 1. Stel short term exposure limit the average airborne concentration over a 15 minute period which should not. Safety data sheet according to 29cfr19101200 and ghs rev. Numerous examples of the use of n buli are to be found in org. Click to download the latest version of adobe reader. Nearly continuous exposure of animals at 250 ppm has caused neurotoxic effects. Identification of the substancemixture and of the companyundertaking 1. Hexanes, acs safety data sheet according to federal register vol. The term may refer to any of the five structural isomers with that formula, or to a mixture of them.
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